Year 2007, Month 4 (Section Full Articles, Page 748)
Porphyrin models of natural catalases
T. N. Lomova, M. E. Klyueva, M. V. Klyuev, and O. V. Kosareva
The kinetics of H2O2 decomposition in the presence of copper complexes with porphyrins, whose structure is regularly changed, was studied by the volumetric method. The ion-molecular mechanism of the reaction was proposed on the basis of spectrophotometric analysis of the intermediates. The use of these complexes as simple models of natural catalases was shown to be promising.
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