Year 2007, Month 4 (Section Full Articles, Page 819)
Spinazarin and ethylspinazarin, pigments of the sea urchin Scaphechinus mirabilis
A. Ya. Yakubovskaya, N. D. Pokhilo, N. P. Mishchenko, and V. F. Anufriev
2,3,5,8-Tetrahydroxy-1,4-naphthoquinone (spinazarin) and 6-ethyl-2,3,5,8-tetrahydroxy-1,4-naphthoquinone (ethylspinazarin) were first isolated from the sea urchin Scaphechinus mirabilis. The structures of spinazarins were established based on analysis of spectroscopic data. A preparative synthetic route to ethylspinazarin was proposed.
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