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ISSUE 6

Year 2007, Month 6 (Section Full Articles, Page 1156)

Microstructure of 1,2-trans and 1,4-transpoly(penta-1,3-dienes)

V. A. Rozentsvet, A. S. Khachaturov, and V. P. Ivanova

Microstructures of 1,2-trans and 1,4-transpoly(penta-1,3-dienes) synthesized using different catalysts were determined by high resolution 13C NMR spectroscopy. The content of dyad combinations of the 1,4- and 1,2-structures was quantitatively determined in hydrogenated poly(penta-1,3-dienes) from the ratio of intensities of the characteristic signals of the carbon atoms of the methylene groups in the 13C NMR spectra.

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