Year 2007, Month 6 (Section Full Articles, Page 1239)
Liquid-phase noncatalytic oxidation of monoterpenoids with nitrous oxide
E. P. Romanenko, E. V. Starokon´, G. I. Panov, and A. V. Tkachev
A series of monoterpenoids differing in the number of double bonds and the pattern of their substitution were tested in the liquidphase noncatalytic oxidation with nitrous oxide (N2O). The structure of olefins has a significant effect on the oxidation route. In the case of terpenoids containing 1,1-disubstituted double bond, norcarbonyl compounds are formed with high selectivity.
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