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ISSUE 10

Year 2007, Month 10 (Section Full Articles, Page 1948)

Synthesis and crystal structure of new double mercury silver phosphide iodide Hg₁₂Ag₄₁P₈₈I₄₁

O. S. Oleneva, T. A. Shestimerova, A. V. Olenev, E. V. Dikarev, and A. V. Shevelkov

New double mercury silver phosphide iodide Hg₁₂Ag₄₁P₈₈I₄₁ (1) was synthesized and its crystal structure was established. Compound 1 crystallizes in the cubic system. The characteristic feature of the crystal structure 1 is the presence of the anionic cage clusters P₁₁^3–, which have been previously found in alkali metal compounds only. The well-ordered P₁₁^3– clusters form a system of polyhedra, which encapsulate various disordered α-AgI-type fragments.

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