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ISSUE 12

Year 2007, Month 12 (Section Full Articles, Page 2443)

New method for the synthesis of (3R,7R)-hexàhydrofarnesyl bromide based on the microwave-activated regioselective enolization of homochiral phytone

M. I. Mallyabaeva, A. Yu. Spivak, T. V. Tyumkina, O. V. Knyshenko, and V. N. Odinokov

Short and efficient synthesis of (3R,7R)-hexàhydrofarnesyl bromide ((3R,7R)-1-bromo3,7,11-trimethyldodecane), the terpenoid synthon for the natural α-tocopherol, has been elaborated based on the microwave-activated regioselective enolization of homochiral phytone.

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