Year 2004, Month 5 (Section Reviews, Page 1065)
Alkylation of carboxylic acid derivatives with
O. G. Kulinkovich
Methods for the generation of dialkoxytitanacyclopropanes (dialkoxytitanium olefin com
plexes) are surveyed. Alkylation of carboxylic acid derivatives with these reagents giving rise to β-titanio ketones and related species, which are spontaneously transformed into the corresponding cyclopropane compounds or react with external electrophiles, are considered.
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