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ISSUE 05

Year 2004, Month 5 (Section Reviews, Page 1065)

Alkylation of carboxylic acid derivatives with dialkoxytitanacyclopropane reagents*

O. G. Kulinkovich

Methods for the generation of dialkoxytitanacyclopropanes (dialkoxytitanium olefin com plexes) are surveyed. Alkylation of carboxylic acid derivatives with these reagents giving rise to β-titanio ketones and related species, which are spontaneously transformed into the corresponding cyclopropane compounds or react with external electrophiles, are considered.

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