Year 2004, Month 5 (Section Reviews, Page 1065)
Alkylation of carboxylic acid derivatives with
dialkoxytitanacyclopropane reagents*
O. G. Kulinkovich
Methods for the generation of dialkoxytitanacyclopropanes (dialkoxytitanium olefin com
plexes) are surveyed. Alkylation of carboxylic acid derivatives with these reagents giving rise to β-titanio ketones and related species, which are spontaneously transformed into the corresponding cyclopropane compounds or react with external electrophiles, are considered.
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