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ISSUE 2

Year 2005, Month 2 (Section Brief Communications, Page 466)

O- and N-Alkylation of N-halosuccinimides in ionic reactions with 1-phenyltricyclo[4.1.0.02,7]heptane

V. A. Vasin,* A. V. Semenov, and V. V. Razin*

N-Bromo- and N-chlorosuccinimides add to 1-phenyltricyclo[4.1.0.02,7]heptane in CH2Cl2 with cleavage of the C(1)—C(7) bond to give isomeric 1 : 1 Markownikoff-type endo,anti-adducts of the norpinane structure in a ~3 : 7 ratio corresponding to N- and O-alkylation of succinimide.

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