Year 2005, Month 5 (Section Full Articles, Page 1125)
Cage complexes as a molecular scaffold for assembling of
polyfunctional and multicentered systems: synthesis and structures of
the first nitroxide clathrochelates*
A. B. Burdukov, E. G. Boguslavskii, V. A. Reznikov, N. V. Pervukhina, M. A. Vershinin,
Ya. Z. Voloshin, O. A. Varzatskii,and Yu. N. Bubnov
The reaction of the reactive clathrochelate FeBd2(Cl2Gm)(BF)2 (Bd and Cl2Gm are the
α-benzyl dioxime and dichloroglyoxime dianions, respectively) with amino-substituted nitroxide
TEMPO-NH2 afforded new mono- and biradical iron(II) mono- and dinitroxide clathrochelate
complexes. The complexes were characterized by X-ray diffraction and spectroscopic (UV—Vis,
ESR, and 57Fe Mössbauer) methods.
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