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ISSUE 5

Year 2005, Month 5 (Section Full Articles, Page 1229)

Synthesis of 2-alkylthio-6-methylpyridine-3-carbaldehydes*

A. A. Zubarev, V. K. Zav´yalova, and V. P. Litvinov

The action of sodium bis(2-methoxyethoxy)aluminum hydride and its complex with piperidine on 2-alkylthio-3-cyano-6-methylpyridines and on their esters in anhydrous ether yielded 2-alkylthio-3-formyl-6-methylpyridines. The aldehydes obtained undergo condensation with malononitrile and methyl cyanoacetate to give the corresponding hetarylidene derivatives.

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