Year 2005, Month 8 (Section Brief Communications, Page 1987)
Effect of H/D isotope substitution on polarizability of methanol molecules
E. V. Ivanov* and V. K. Abrosimov
The electron polarizabilities (α0•1024/cm3 molec.–1) were estimated from the data on
refractive indices and molar volumes of H/D isotopomers of methanol at 25 °C using
the Lorentz—Lorentz formula: 3.265 (ÑÍ3ÎÍ), 3.260 (ÑÍ3OD), 3.235 (CD3OH), and
3.231 (CD3OD). A relationship between the isotope effects for α0 and volume (packing)
changes in the structure of liquid methanol induced by deuterosubstitution in the methanol
molecule was proposed.
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