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Year 2005, Month 9 (Section Brief Communications, Page 2211)

New antiferromagnetic tetranuclear pivalate complex containing FeIII and FeII atoms*

M. A. Kiskin, A. A. Sidorov, G. G. Aleksandrov, Yu. G. Shvedenkov, V. N. Ikorskii, V. M. Novotortsev, I. L. Eremenko, and I. I. Moiseev

The interaction of [K2FeIII 4(O)2(OOCCMe3)10(HOOCCMe3)2(H2O)2]n with 2-pyridinecarboxaldehyde results in a mixed-valence complex FeIIFeIII 3(μ3-O)2(μ2-OOCCMe3)7L2• •2.5MeCN•3H2O (L = 2-NC5H4COOH0.75K0.25). The structure of the complex was established by X-ray analysis. The magnetic properties of the complex were studied.

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