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ISSUE 10

Year 2005, Month 10 (Section Full Articles, Page 2379)

Regioselectivity of reductive debromination of substituted pentabromobenzenes with sodium tert-butoxide in DMSO

V. N. Shishkin (a), I. V. Tarasova (a), and K. P. Butin (b)†

The regioselectivity of reductive debromination of substituted pentabromobenzenes C6Br5X (X = NH2, OMe, Me, H, Cl, F, and NO2) under the action of ButONa in DMSO containing ButOH has been studied. The reaction followed the halophilic mechanism via carbanions.

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